Term

Erhan Karaca

Overview

最終更新: 2026年7月9日

高温超電導技術の専門家であり、VEIR社においてデータセンター向けHTSケーブルシステムの技術開発を指揮している。

Mentioned Articles

1 件

Research Papers

5 件
  • Electrochemical synthesis of PPy composites with nanostructured MnOx, CoOx, NiOx, and FeOx in acetonitrile for supercapacitor applications

    Erhan Karaca, Dincer Gokcen, N. Pekmez, K. Pekmez

    201938 件引用Semantic Scholar

    Abstract In the present study, the polypyrrole (PPy) composites with nano-structured CoOx, NiOx, MnOx, and FeOx were synthesized using the galvanostatic method on their own metal-intercalated graphite surfaces. The deposition and intercalation are performed in TBABF4/acetonitrile solution with related metal (II) tetrafluoroborate salts, pyrrole, HBF4, H2O, Triton-X 100 (TX100) and carboxymethyl cellulose (Na-CMC). For the PPy/MnOx/Na-CMC composite, the effects of intercalation and additives on the specific capacitance were examined in an H2SO4/water medium by using cyclic voltammetry (CV) and the Electrochemical Impedance Spectroscopy (EIS). Using the optimum deposition conditions determined for Mn composite (additive concentrations and galvanostatic parameters), PPy/CoOx/Na-CMC, PPy/NiOx/Na-CMC, and PPy/FeOx/Na-CMC coatings with a mass loading of 4.0 mg cm−2 were deposited on their own metal-intercalated graphite electrodes in the deposition solutions containing Co(BF4)2, Ni(BF4)2 and Fe(BF4)2, respectively. XRD, TEM, XPS, SEM-EDX, BET, and EIS techniques were used in characterizing the coatings. Subsequently, the capacitive properties of the composite coatings were examined by means of the galvanostatic charge-discharge test. The highest SC value is recorded for the Mn-based composite (463 F g−1), whereas the lowest is for Fe-based (311 F g−1) one. Finally, symmetric and asymmetric supercapacitor configurations incorporating two electrodes with 10 mg cm−2 active material were used in making measurements to determine the capacitive behaviors of PPy/Metal oxide composites. The symmetric supercapacitor with PPy/MnOx/Na-CMC composite providing 0.29 kW kg−1 and 15.0 Wh.kg−1 at 0.5 A g−1 maintains 62% of its power and energy densities at 2.5 A g−1 at the end of 5000 cycles at a potential range of 0.8 V.

  • A facile one-step electrosynthesis of polypyrrole/nano-SbOx composite for supercapacitors

    Meliha Gözde Çekiç, Erhan Karaca, N. Pekmez

    202314 件引用Semantic Scholar
  • Electrosynthesis of binder-free polypyrrole/nano- Bi2O3-Bi2O2CO3 composite for supercapacitor anode

    Erhan Karaca

    202312 件引用Semantic Scholar
  • Fabrication of a PPy composite with EMD nanorods recovered from Li-ion batteries for supercapacitor

    Erhan Karaca, N. Pekmez, K. Pekmez

    20246 件引用Semantic Scholar
  • In situ electrosynthesis of polypyrrole/nano Bi_2O_4 composite for supercapacitor applications

    Erhan Karaca

    20235 件引用Semantic Scholar